Synthesis and nonlinear optical properties of a novel polyurethane containing cyanovinylthiophene with enhanced thermal stability of dipole alignment for electro‐optic applications

Stabilization of electrically induced dipole alignment is one of the important criteria in the development of nonlinear optical (NLO) polymers for electro‐optic device applications. Polyurethanes for NLO applications have attracted attention because of their high thermal stability due to hydrogen bonding. In the work reported here, we designed and synthesized a new type of NLO polyurethane, in which the pendant NLO chromophores are part of the polymer backbone. This mid‐type NLO polymer is expected to have the merits of both main‐chain and side‐chain NLO polymers, namely stable dipole alignment and good solubility. 1‐[3,4‐Di‐(2‐hydroxyethoxy)phenyl]‐2‐(2‐thienyl)ethene was prepared and condensed with 3,3′‐dimethoxy‐4,4′‐biphenylenediisocyanate to yield a polyurethane. This polyurethane was reacted with tetracyanoethylene to give a novel Y‐type polyurethane (7) containing 1‐(3,4‐dioxyphenyl)‐2‐[5‐(1,2,2‐tricyanovinyl)‐2‐thienyl]ethenes as NLO chromophores, which constitute part of the polymer backbone. Polyurethane 7 is soluble in common organic solvents such as N,N‐dimethylformamide and dimethylsulfoxide. It shows a thermal stability up to 280 °C from thermogravimetric analysis with a glass transition temperature obtained from differential scanning calorimetry of ca 162 °C. The second harmonic generation (SHG) coefficient (d₃₃) of a poled polymer film of he polyurethane at 1560 nm fundamental wavelength is ca 1.11 × 10^?18 C. Polymer 7 exhibits an enhanced thermal stability and no significant SHG decay is observed below 150 °C, which is acceptable for NLO device applications. Copyright © 2009 Society of Chemical Industry     

Silver-ion high-performance liquid chromatographic separation and identification of conjugated linoleic acid isomers

This is the first report of the application of silverion impregnated high-performance liquid chromatography (Ag⁺-HPLC) to the separation of complex mixtures of conjugated linolenic acid (CLA) isomers present in commercial CLA sources and foods and in biological specimens. This method showed a clear separation of CLA isomers into three groups related to their trans,trans, cis,trans or trans,cis, and cis,cis configuration of the conjugated double-bound system. In addition, this method separated within each geometrical isomeric group. Following Ag⁺-HPLC isolation, gas chromatography (GC)-electron impact mass spectrometry, and GC-direct deposition-Fourier transformed infrared spectroscopy were used to confirm the identity of two major positional isomers in the cis/trans region, i.e., Δ8,10- and Δ11,13-octadecadienoic acid, which had not been chromatographically resolved previously, Furthermore, the potential of this method was demonstrated by showing different Ag⁺-HPLC profiles exhibiting patterns of isomeric distributions for biological specimens from animals fed a diet containing a commerical CLA preparation, as well as for a commerical cheese product.     

Effect of extrinsic impedance and parasitic capacitance on figure of merit of RF MOSFET

This paper investigates the impact of source/drain impedance, gate-to-bulk capacitance, and gate resistance on device properties from 0 to 50 GHz for 0.13-/spl mu/m MOSFETs. Better device characteristics (g/sub m/ and C/sub gg/) can be found on MOSFETs with lower metal (or source/drain) resistance. But the best frequency characteristics (f/sub T/ and f/sub max/) occurred on MOSFETs with medium metal (or source/drain) resistance due to the increased interconnection capacitances. For radio frequency MOSFETs with finger-gate structure, better high-frequency behavior occurred on devices with medium finger-gate width W/sub f/ because of the tradeoff between gate (or source/drain) resistance and parasitic capacitance.     

Spiral grain—An adaptation of trees to withstand stem breakage caused by wind-induced torsion

Expressions are derived for the internal mechanical stress components in trees when exposed to bending and torsion by wind forces. The crown is modeled as rectangular, and the stem taper so that the maximum bending stress is equal at all heights. Trees with asymmetric crowns will undergo torsion as well as bending, and the shear stresses associated with torsion are determined and compared to the bending stresses. The results show that shear failure is likely to occur relatively high up on the stem when the crown asymmetry is a few decimeters. The fact that torsion might be critical to the strength of trees towards wind forces, introduces an explanation to spiral grain growth. It is shown that spiral grain in the direction of the wind-induced torque improves the bending strength of the tree. Spiral grain is therefore beneficial for trees with a prevailing external torque.     

Untersuchungen zum Einfluß der Probendicke auf das Verformungs- und Bruchverhalten bauteilähnlicher Großzugproben

Influence of specimen thickness on the deformation and fracture behaviour of wide plates The influence of specimen thickness on the deformation behaviour and the load bearing capacity has been investigated with large scale double-edge-notched-tension-specimens (DENT). The difference of the state of stress can be modelled by simplifications (plain strain, plain stress). Equations for the calculation of plastic limit loads taking into account the defect ratio a/W have been derived based on analytical, numerical and experimental investigations. Already existing equations may lead to unsafe prediction in special situations. The difference between plastic limit and maximum load is smaller for the thicker specimens due to higher toughness requirements. The toughness requirements have been quantified for the DENT-specimens using the J-integral analysis. The requirements mainly depend on the overall dimensions (W, B), the thickness ratio (B/W) and the defect ratio (a/W).     

Mechanisms and solutions to gate oxide degradation in flash memory by tunnel-oxide nitridation engineering

Increasing attention has been paid to the peripheral gate-oxide integrity degradation of Flash memory devices that is induced by the tunnel-oxide nitridation. In this letter, the mechanisms of tunnel-oxide nitridation-induced degradation are characterized. We report that both a local oxide thinning effect and nitrogen residue will impact the integrity of gate-oxide. Minimizing the local thinning effect with an in situ steam generation (ISSG) oxidation process and removing the nitrogen residues from the silicon wafer surface by either an additional sacrificial oxide process or over-dip are proven to be useful in recovering the gate-oxide integrity. An optimum approach with the tunnel-oxide nitridation is proposed in this work that results in comparable or even better gate-oxide property than other approaches that have no tunnel-oxide nitridation process.     

The effect of different exposure conditions on the biofilm/copper interface

The effects of the different exposure conditions on the electrochemical behavior of copper were evaluated in a growth medium containing Shewanella oneidensis MR-1. Impedance spectra were recorded at the corrosion potential (E_corr) in three different cells for one week of exposure followed by cyclic voltammetry. A second time constant was observed in the impedance spectra of copper that was partially immersed in the test cell, where the electrode was in contact with an air/liquid interface (cell B). These spectra resembled those usually observed for metals covered with a polymer coating. Complete immersion of copper in the electrolyte (no air/liquid interface) or deaeration of cell B resulted in one-time-constant spectra that are typical of those found for passive metals. Excellent corrosion protection was provided by MR-1 regardless of exposure condition. E_corr increased with time for the partially immersed Cu electrode exposed to the aerated solution in cell B, while it decreased for the other two exposure conditions. Cathodic polarization curves recorded after exposure for 7 days showed two reduction peaks for copper tested in cell B, while no reduction peaks were observed for the other cases. Similar results were obtained using cyclic voltammetry.     

Determination of compounding formulation of cured rubber by reverse engineering

The present work deals with reverse engineering on four rubber formulations. Information about the material composition of the compounding formulations was obtained by using techniques such as acetone extract, thermogravimetric analysis, energy dispersive X‐ray fluorescence studies, and Fourier transform infrared (FTIR) spectroscopy in attenuated total reflection mode. The reverse engineered formulations were compared on a qualitative and quantitative basis with the initial formulations. The aim was to ascertain the validity of the methodology, which may be used as reverse engineering of rubber compounds to quantitatively analyze unknown ground tire rubber in future. The state of the art was based on a fractional mass transfer from acetone extract to the rubbers detected in TGA. Through this new approach, the formulations calculated were very consistent with the formulations employed, thus establishing the validity of the methodology used. POLYM. ENG. SCI., 55:1450–1458, 2015. © 2015 Society of Plastics Engineers     

Fundamental periods of steel eccentrically braced frames

This paper describes formulation of a hand method that can be used to estimate the computed fundamental periods of vibration of building structures in general and steel eccentrically braced frames (EBFs) in particular. The developed method uses the Rayleigh's method as a basis and utilizes the roof drift ratio (RD_R) under seismic forces as a parameter. To obtain RD_R, more than 4000 EBFs were designed by considering the seismic hazard, number of stories, braced bay width and link length to bay width ratio as prime variables. A model was developed to estimate RD_R, which depends on the rigid plastic deformation mechanism for a typical EBF. The method was verified using design data produced as a part of this work as well as data published in literature. The verifications indicate that the proposed formulation is capable of providing acceptable estimates of the computed period. When compared with existing empirical period–height relationships, the proposed formulation offers closer estimates with reduced scatter. The method was further refined to derive new period–height relationships for two different seismicity regions. The accuracy of the relationship for high seismic regions was verified using measured periods of EBF buildings. Copyright © 2014 John Wiley & Sons, Ltd.